Journal
ORGANOMETALLICS
Volume 29, Issue 21, Pages 4778-4780Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om100335j
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Funding
- National Science Foundation [CHE-0608142, CHE-0953484, CHE-0749868, CHE-0716718]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [0953484] Funding Source: National Science Foundation
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The lithiated N-heterocyclic carbene-phosphinidene adduct L':P-H (3; L': = :C{[N(2,6-(Pr2C6H3)-C-i)](2)CMCLi-(THF)(3)}) unexpectedly resulted from the reaction of lithium metal with the carbene-stabilized diphosphorus species L:P-P:L (2: L: = :C{N(2,6-(Pr2C6H3)-C-i)CH}(2)). Compound 2 was previously prepared by the potassium graphite reduction of L:PCl3 (1).
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