Journal
ORGANOMETALLICS
Volume 29, Issue 18, Pages 4090-4096Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om1006566
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- BP
- NSF [CHE-0639094]
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Oxidation of (Idipp)AuMe (Idipp = 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene) with I, gives a monomethyl Au(III) complex, (Idipp)Aul(2)Me, which decomposes cleanly to MeI and (Idipp)AuI. Kinetics experiments show that this transformation occurs primarily via three-coordinate, cationic [(Idipp)AuIMe](+), which undergoes intramolecular reductive elimination rather than nucleophilic attack by external I-.
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