Journal
ORGANOMETALLICS
Volume 29, Issue 11, Pages 2400-2402Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om100290h
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- Ministry of Education, Culture, Sports, Science and Technology of Japan
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Deprotonation of the selenoformyl group in N,N-dibenzyl selenoformamide with LDA, followed by silylation and germylation of the resulting anion with Me(3)SiCl and Me(3)GeCl, gives (selenocarbamoyl)silane and -germane in moderate to good yields. The molecular structures of these products and the starting selenoformamide were characterized by using X-ray analyses.
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