Journal
ORGANOMETALLICS
Volume 29, Issue 18, Pages 4004-4006Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om100747j
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Funding
- Taiwan National Science Council [NSC: 97-2113-M-001-024-MY2]
- Academia Sinica
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We have obtained boronium complexes upon reaction of an amino-NHC lithium bromide adduct with borane. Unexpectedly, the treatment of the boronium complexes with silver triflate led to the isolation of a bis-borane compound containing two chemically different boron centers. The bis-borane and boronium complexes can interconvert via a four-membered intermediate metallacycle consisting of a three-center, two-electron B-H-B bonding motif assisted by the pendant amine arm.
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