4.5 Article

Bis(NHC)-Palladium(II) Complex-Catalyzed Dioxygenation of Alkenes

Journal

ORGANOMETALLICS
Volume 29, Issue 4, Pages 928-933

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/om900975a

Keywords

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Funding

  1. Shanghai Municipal Committee of Science and Technology [06XD14005, 08dj1400100-2]
  2. National Basic Research Program of China [973-2009CB825300]
  3. National Natural Science Foundation of China [20472096, 20872162, 20672127, 20821002, 20732008]

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Bis(NHC)-Pd(II) complexes derived from 1,1'-binaphthyl-2,2'-diamine (BINAM) were successfully first used to catalyze the dioxygenation of alkenes under mild conditions tolerant of air and moisture. Cationic NHC-Pd2+ diaquo complex le showed the highest catalytic activity to give 1,2-dioxygenation products with good syn-diastercoselectivity for 1,2-disubstituted alkenes.

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