Journal
ORGANOMETALLICS
Volume 29, Issue 22, Pages 5972-5981Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om100756p
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- NSERC (Canada)
- University of Western Ontario
- Ontario Photonics Consortium
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A variety of terminal alkynes were added to Mes(2)Si=CHCH(2)t-Bu, 4, a naturally polarized silene. Three different modes of reactivity were observed: addition across the acetylenic C-H bond to give silylacetylenes 6a-i and 12, cycloaddition to give silacyclobutenes 7 and 9, and ene-addition to give vinylsilane 8. The reactivity of the naturally polarized silene 4 toward terminal alkynes is compared to that of nonpolar silenes.
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