4.5 Article

Unprecedented CpLi Ammoniacates

Journal

ORGANOMETALLICS
Volume 29, Issue 23, Pages 6169-6171

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/om100831v

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Funding

  1. Center of Materials Crystallography
  2. Deutsche Forschungsgemeinschaft [1178]
  3. Volkswagenstiftung

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CpLi aggregates from ammonia: [(CpLi)(2)(NH3)(3)] (1) contains syn-arranged lithocene with an additional eta(1) coordination of Li(NH3)(3), and[Li(NH3)(4)][Cp](2)features naked Cp anions and [Li(NH3)(4)](+) cations arranged to channel walls generated from cationic meshes.

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