Journal
ORGANOMETALLICS
Volume 29, Issue 2, Pages 403-408Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om900864r
Keywords
-
Categories
Funding
- NSF
- NIH [5R01 GM31332]
- NDSEG
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [0809418] Funding Source: National Science Foundation
Ask authors/readers for more resources
Ru-based olefin metathesis catalysts containing, carbohydrate-derived NHCs from glucose and galactose were synthesized and characterized by NMR spectroscopy. 2D-NMR spectroscopy revealed the presence of Ru-C (benzylidene) rotamers at room temperature, and the rate of rotation was measured using magnetization transfer and VT-NMR spectroscopy. The catalysts were found to be effective at ring-opening metathesis polymerization (ROMP), ring-closing metathesis (RCM), cross-metathesis (CM), and asymmetric ring-opening cross-metathesis (AROCM) and showed surprising selectivity in both CM and AROCM.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available