4.5 Article

Probing the Mechanism of Aldehyde Addition to a Disilene and Two Silenes: Solvent Effects

Journal

ORGANOMETALLICS
Volume 29, Issue 5, Pages 1305-1308

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/om900673n

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Funding

  1. Natural Sciences and Engineering Research Council of Canada
  2. University of Western Ontario

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The effect of changing the solvent from a hydrocarbon to acetonitrile on the mechanism of the addition of aldehydes to a disilene and two silenes was investigated. The products of the reaction between Mes(2)si=CH(CH2-t-Bu) and acetonitrile were characterized.

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