Journal
ORGANOMETALLICS
Volume 29, Issue 3, Pages 523-526Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om9009125
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- Ecole Superieure de Chimie Physique Electronique de Lyon (ESCPE Lyon)
- CNRS
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The complex pd(TPPTS)(3) reacts in water at room temperature with butenols (ionization) or butadiene (protonation) to produce two isomeric hydrosoluble eta(3)-allylic palladium complexes ([Pd(syn-C-4)(TPPTS)(2)](+) and [Pd(anti-C-4)-(TPPTS)(2)](+)) and three isomers of butenylphosphonium salts of TPPTS. The pH has a great influence on the reaction rates and on the stability of the products.
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