4.5 Article

Solvent-Enhanced Coupling of Sterically Hindered Reagents and Aryl Chlorides using Functionalized Ionic Liquids

Journal

ORGANOMETALLICS
Volume 28, Issue 4, Pages 937-939

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/om801083c

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Funding

  1. EPFL-PKU
  2. China Scholarship Council
  3. Natural Science Foundation of China [20773005, 20533010]

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A highly efficient and poison-resistant system for the Suzuki reaction based on hydroxyl-functionalized ionic liquids has been established. The ionic liquid plays a critical role in catalyst/substrate activation directly facilitating ligand-free coupling reactions.

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