Journal
ORGANOMETALLICS
Volume 28, Issue 1, Pages 48-50Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om801092a
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Funding
- Scientific Research for Young Scientists [19675002]
- Ministry of Education, Culture, Sports, Science and Technology of Japan [18066003]
- Grants-in-Aid for Scientific Research [18066003] Funding Source: KAKEN
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The ruthenium-catalyzed oxypropargylation of alkenes with propargylic alcohols and simple alcohols has been found via ruthenium-allenylidene complexes as key intermediates. As a synthetic application, an intramolecular cyclization using this method has been developed to give the corresponding anti-1-alkoxy-3-ethynylindanes in high to excellent yields with a high diastereoselectivity.
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