Journal
ORGANOMETALLICS
Volume 28, Issue 21, Pages 6374-6377Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om9007696
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- Deutsche Forschungsgemeinschaft
- Alexander von Humboldt Stiftung
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Reactions of silicon halides with N-heterocyclic carbene produce neutral penta- of hexacoordinate complexes IPr center dot SiF4 (1), IPr center dot SiF4 center dot IPr (2), and IPr center dot SiBr4 (3) (IPr = :C[N(2,6-iPr(2)-C6H3)-CH](2)). Molecular structures of 1-3 were determined by X-ray diffraction studies and exhibit interesting structural features.
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