Journal
ORGANOMETALLICS
Volume 28, Issue 16, Pages 4845-4851Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om900402e
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Funding
- Natural Science and Engineering Research Council (NSERC) of Canada
- NSERC and the Alberta Ingenuity Fund
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A methodology for the incorporation of fluoroaryl groups into boron dipyrrinato complexes (modified BODIPY dyes) is reported. Two hexaalkylated dipyrrinato ligands with either H or CH3 occupying the meso position were employed; when they were treated with fluoroaryl haloboranes in the presence of a weak base, the title compounds were prepared in good to excellent yields. The structures of seven derivatives were determined using X-ray crystallography, and their spectroscopic, photophysical, and redox properties are compared.
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