Journal
ORGANOMETALLICS
Volume 28, Issue 17, Pages 5191-5195Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om900444z
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Funding
- National Natural Science Foundation of China [20725205]
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Reaction of cyclic diaminochlorosilanes with 1,3-bis(tert-butyl)imidazol-2-ylidene resulted in the facile formation of the corresponding stable and transient diaminosilylenes. This novel dehydrochlorination route could be applied for the generation of four- and five-membered N-heterocyclic silylenes with a range of different substituents under very mild conditions. Activation of an olefinic C-H bond and reduction of a cyclic diaminochlorosilane have been observed for these new transient silylenes.
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