Journal
ORGANOMETALLICS
Volume 28, Issue 1, Pages 321-325Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om800821q
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Funding
- U.S. Department of Energy
- ELOS
- NSERC Canada
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Air-stable Ir and Ru complexes of a chelating pyrimidine-functionalized N-heterocyclic carbene were synthesized. The complexes were characterized by NMR spectroscopy and single-crystal X-ray diffraction and were found to be catalytically active for transfer hydrogenation, beta-alkylation of secondary alcohols with primary alcohols, and N-alkylation of amines with primary alcohols. Notably, the Ir complexes were found to catalyze the N-alkylation of amines using the mild base NaHCO3.
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