Journal
ORGANOMETALLICS
Volume 28, Issue 1, Pages 45-47Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om801046d
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- Spanish Ministerio de Educacion y Ciencia (MEC) [CTQ2007-62814]
- Consolider-Ingenio 2010 [CSD2007-0006]
- Junta de Andalucia [FQM-3151, FQM-672]
- CONACYT [229340]
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The Rh(I) cyclopentadienyl olefin compounds [(C5Me4R)Rh(olefin)(2)] (R = CMe3, SiMe3, SiMe2CMe3; olefin = C2H4, C2H3SiMe3) are readily prepared from the corresponding [RhCl(olefin)212 and zincocene, [Zn(C5Me4R)(2)], precursors. The new compounds undergo hydrogen/deuterium exchange at the olefinic sites in deuterated benzene, at a rate dependent on the cyclopentadienyl substituents.
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