Journal
ORGANOMETALLICS
Volume 28, Issue 8, Pages 2625-2628Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om900084y
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- American Chemical Society
- NIH [CHE-0308640]
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When the insoluble dimers [Rh(COD)X](2) (X = OH-, Cl-) are in. contact with a basic aqueous solution of hydroquinone dianion, the precipitate dissolves to afford (benzoquinone)Rh(COD)(-) (2). Complex 2 is very stable and can be recycled many times as a homogeneous catalyst for the conjugate addition of boronic acids to olefins. NMR spectra suggest their the catalytic species is indeed the quinone complex 2.
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