4.5 Article

Isolation and Characterization of a Nucleophilic Allylic Indium Reagent

Journal

ORGANOMETALLICS
Volume 28, Issue 7, Pages 1998-2000

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/om900096r

Keywords

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Funding

  1. Chemistry of Concerto Catalysis [18065015, 20036036]
  2. Synergistic Effects for Creation of Functional Molecules [19550038]
  3. Ministry of Education, Culture, Sports, Science and Technology of Japan

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Transmetalation between allylic stannanes and indium halides gave allylic indium dihalides. The bond length of In-C is 2.172 angstrom, which is close to the reported average indium-carbon bond length. The isolated allylic indium dibromide with two phthalan ligands showed nucleophilicity for a carbonyl compound.

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