Journal
ORGANOMETALLICS
Volume 28, Issue 8, Pages 2352-2355Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om8011163
Keywords
-
Categories
Funding
- Petroleum Researcb Foundation (PRF-G)
- American Chemical Society
Ask authors/readers for more resources
4,5-Disubstituted NH-1,2,3-triazoles (TRIA) were used to coordinate with Rh(I) metal cation, forming a new class of triazole-bridged [Rh(COD)(TRIA)](2) complexes in near-quantitative yields. X-ray crystallography studies revealed that the C-4-substituted groups effectively controlled the triazole binding sites, resulting in different coordination patterns. In addition, these air- and moisture-stable [Rh(COD)(TRIA)](2) complexes showed affective catalytic properties in Pauson-Khand reactions, with superior stability.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available