Journal
ORGANOMETALLICS
Volume 28, Issue 7, Pages 1988-1991Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om8011085
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Funding
- Ministry of Education, Culture, Sports, Science and Technology of Japan [18064014]
- Grants-in-Aid for Scientific Research [18064014] Funding Source: KAKEN
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Three Ti-M-2 (M-2=Ni, Pd, Pt) heterobimetallic complexes, [(eta(3-)methallyl) M-2((Ph2PNBu)-Bu-t)(2)TiCl2](OTF), were synthesized in which a Ti-IV <- M-2 interaction was suggested by crystallography and DFT calculations. The Ti-IV <- M-2 interaction enhanced electrophilicity of the eta(3)-methallyl ligand of M-2, leading to high reactivity of the eta(3)-methallyl moiety with Et2NH compared with that of the dppp analogue.
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