Journal
ORGANOMETALLICS
Volume 28, Issue 17, Pages 5240-5243Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om900489d
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Funding
- Ministry of Education, Culture, Sports, Science and Technology, Japan [19675002, 18066003]
- TEPCO Research Foundation
- Grants-in-Aid for Scientific Research [18066003, 19675002] Funding Source: KAKEN
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We have designed and prepared novel diphosphine ligands bearing an OS(tpy)(2)(2+) moiety as a light-harvesting unit and have found that these diphosphine ligands coordinate to the rhodium atom in a bidentate manner. The rhodium complexes including diphosphine ligands bearing an OS(tpy)(2)(2+) moiety have been revealed to work as an effective photocatalyst for the production of dihydrogen.
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