4.5 Article

fac-Tricarbonyl Rhenium(I) Azadipyrromethene Complexes

Journal

ORGANOMETALLICS
Volume 28, Issue 20, Pages 5837-5840

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/om900552e

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Funding

  1. National Science Foundation [CHE-0749086, CHE-0748982, CHE-0541766]
  2. Republic of Turkey Ministry of National Education
  3. Division Of Chemistry
  4. Direct For Mathematical & Physical Scien [0749086] Funding Source: National Science Foundation

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Rhenium(I) complexes of azadipyrromethene ligands are reported: three have been characterized crystallographically. The free ligands and their metallo-complexes undergo reductive electrochemistry. Red-light absorption results from optically, allowed transitions to a ligand-localized LUMO.

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