4.5 Article

A facile and practical synthetic route to 1,1′-bis(o-carborane)

Journal

ORGANOMETALLICS
Volume 27, Issue 19, Pages 5167-5168

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/om8005323

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Funding

  1. Research Grants Council of the Hong Kong SAR [403907, 2060340]

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Reaction of dilithiocarborane (1,2-Li2C2B10H10) with CuCl in toluene affords a single product, 1,1':2,2'-[Cu(toluene)](2)(C2B10H10)(2), which gives 1,1'-bis(o-carborane) after hydrolysis. This serves as the most efficient method for the preparation of 1,1'-bis(o-carborane).

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