Journal
ORGANOMETALLICS
Volume 27, Issue 10, Pages 2287-2292Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om8000229
Keywords
-
Categories
Ask authors/readers for more resources
A new complex of ruthenium bearing the unsaturated N-heterocyclic carbene IMes (IMes = 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene) and an ionic alkylidene moiety was synthesized and fully characterized. The X-ray structure of this catalyst and that of its SIMes (SIMes = 1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidene) analogue were determined. The catalytic performances of these catalysts and their recyclability were investigated for olefin cross-metathesis in a [Bmim][PF6]/ organic solvent biphasic medium. The results show the importance of the proper choice of organic solvent. The solvent effect/catalytic behavior could be explained in terms of clathrate formation.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available