Journal
ORGANOMETALLICS
Volume 27, Issue 17, Pages 4277-4279Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om8005239
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Funding
- Agency for Science, Technology & Research (Singapore)
- National University of Singapore (NUS) [R143-000-277-305]
- CNRS
- Ministere de la Recherche (Paris)
- French Embassy in Singapore
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Cr(III) complexes with [NON] and [NSN] heteroscorpionate ligands derived from bis(pyrazol-1-yl)methane have been prepared, which are active for ethylene trimerization to 1-hexene with high selectivity. Structural studies have established the coordination of the ether or thioether pendant group, which leads to a bicyclic metallaheterocycle flanked by pyrazoyl rings.
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