Journal
ORGANOMETALLICS
Volume 27, Issue 21, Pages 5521-5524Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om800644m
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- University of California Riverside
- CNRS
- Donors of the American Chemical Society Petroleum Research Fund [44734-AC1]
- National Science Foundation [CHE-0719039]
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A 2-terthienylphospholide can be prepared from a 1-terthienylphosphole by reaction with tBuOK in diglyme at 150 degrees C. This phospholide is then transformed into the corresponding 1-methyl-2-terthienylphosphole-borane. This borane complex fluoresces at 5 10 nm in CH2Cl2 with a quantum yield of 0.17. The excited-state displays a significant charge transfer between the terthienyl substituent and the phosphole ring as shown by the shift of the emission to lower energies upon increasing the polarity of the solvent.
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