Journal
ORGANOMETALLICS
Volume 27, Issue 19, Pages 4837-4840Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om800755x
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Funding
- EPSRC
- CHS, Newcastle University
- Johnson Matthey
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Cationic rhodium complexes based on (R)-BINAP catalyze the sequential double [2 + 2 + 2] cycloaddition between 1,4-bis(diphenylphosphinoyl)buta-1,3-diyne and an internal 2,n-diyne followed by its terminal counterpart in an operationally straightforward procedure to afford pseudo-C-2-symmetric axially chiral biaryl diphosphines in good yield and with exceptionally high enantioselectivity.
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