4.5 Article

Ruthenium-catalyzed intramolecular cyclization of 3-butyne-1,2-diols into furans

Journal

ORGANOMETALLICS
Volume 27, Issue 14, Pages 3614-3617

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/om800298r

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Ruthenium-catalyzed intramolecular cyclization of 3-butyne-1,2-diols affords the corresponding substituted furans in good to high yields. This catalytic reaction is proposed to proceed via ruthenium-allenylidene complexes as key intermediates.

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