Journal
ORGANOMETALLICS
Volume 27, Issue 15, Pages 3630-3632Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om8003652
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Carbon monoxide or an aryl isocyanide promotes a benzylidene carbene transfer from ruthenium to tricyclohexylphosphine in the first-generation Grubbs carbene complex. The resulting ruthenium(II) complexes have been isolated and structurally characterized by X-ray crystal structure analysis; a probable mechanism for the ligand-promoted transformation is also discussed.
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