Journal
ORGANOMETALLICS
Volume 27, Issue 16, Pages 4254-4259Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om800377m
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Funding
- MEC of Spain [CTQ2005-05187]
- Bancaixa [P1.1B2007-04]
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A series of five different (p-cymene)Ru(NHC) complexes (NHC = imidazolin-2-ylidene, imidazolin-4-ylidene, and pyrazolin-3-ylidene) have been obtained and fully characterized. The crystal structure of two of the new complexes has been determined by X-ray diffraction methods. All five complexes have been tested in the catalytic beta-alkylation of secondary alcohols with primary alcohols and the dimerization of phenyl acetylene, showing an excellent activity in both processes. A clear improvement on the catalytic activity of the complexes is observed when the more basic NHC ligands are used. The pyrazolylidene-Ru complex lies among the best catalysts for the beta-alkylation of secondary alcohols reported to date.
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