Journal
ORGANIC PROCESS RESEARCH & DEVELOPMENT
Volume 13, Issue 2, Pages 349-353Publisher
AMER CHEMICAL SOC
DOI: 10.1021/op800278g
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- Evonik Rohm GmbH
- state of Mecklenburg-Vorpommern
- Federal Ministry BMBF, and the Deutsche Forschungsgemeinschaft (Leibniz-Price)
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The synthesis of octadienyl-substituted alcohols via palladium-catalyzed telomerization is described. 2-N-Methylaminoethanol, ethylene glycol, and 1,2-propylenediol react smoothly with 1,3-butadiene to give valuable intermediates for speciality polymers in high selectivity and quantitative yield on multi-100 g-scale.
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