Journal
ORGANIC LETTERS
Volume 20, Issue 19, Pages 6265-6269Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b02746
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Funding
- 13th-Five Key Project of the Chinese Academy of Sciences [Y7720519KL]
- QIBEBT
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A new NNN pincer (amine-pyridine-imine, API) cobalt complex, which is bench-stable and is applicable for the highly efficient and regioselective hydrosilylation of terminal alkynes, is developed. A broad set of alpha-vinylsilanes was successfully synthesized in good to high yields with up to 98/2 Markovnikov regioselectivity. This protocol can be readily scaled up for gram-scale synthesis and demonstrates the most efficient cobalt-catalyzed hydrosilylation of alkynes with turnover frequencies as high as 126 720 h(-1) to date.
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