Journal
ORGANIC LETTERS
Volume 20, Issue 19, Pages 6161-6165Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b02629
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Funding
- Recruitment Program of Global Experts (1000 Talents Plan)
- Natural Science Foundation of Fujian Province [2016J01064]
- Fujian Hundred Talents Plan
- Program of Innovative Research Team of Huaqiao University [Z14X0047]
- Subsidized Project for Cultivating Postgraduates' Innovative Ability in Scientific Research of Huaqiao University
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An unprecedented Cu-catalyzed oxidative cleavage of two C-N bonds of 3-aminoindazoles is reported herein, which represents the first example for denitrogenative ring-opening of 3-aminoindazoles. This novel reactivity of 3-aminoindazoles enables the production of diverse aromatic nitrile-containing (hetero)arenes via C-H arylation of (hetero)-arenes with wide subsrate scope under mild conditions.
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