Journal
ORGANIC LETTERS
Volume 20, Issue 18, Pages 5813-5816Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b02511
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Funding
- National Natural Science Foundation of China [81630097, 81602984]
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Three unusual sesquiterpenoid dimers, nardochinoids A-C (1-3), were isolated from Nardostachys chinensis Batal. Comyound 1 features a rare fused 3,8-dioxatricyclo [7.2.1.0(1,6)]dodecane-11-one ring system, compound 2 is the first nitrogen-containing nornardosinane-aristolane sesquiterpene conjugate, and compound 3 represents the first example of the dimer of a nornardosinane and a nardosinane sesquiterpene. Their structures were characterized by NMR spectroscopic methods and X-ray single-crystal diffraction analysis. Compound 3 showed significant anti-inflammatory activities.
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