Journal
ORGANIC LETTERS
Volume 20, Issue 18, Pages 5861-5865Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b02537
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- DST, New Delhi
- CSIR, New Delhi
- CBMR, Lucknow
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A straightforward synthesis of amides, ureas, and esters is reported by visible-light cross-dehydrogenating coupling (CDC) of aldehydes (or amine carbaldehydes) and amines/R-OTBS ethers by photoredox catalysis. The reaction is found to be general and high yielding. A plausible mechanistic pathway has been proposed for these transformations and is supported by appropriate controlled experiments.
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