Journal
ORGANIC LETTERS
Volume 20, Issue 17, Pages 5291-5295Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b02231
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Funding
- Natural Science Foundation of Shandong Province [ZR2018MB009, ZR2016JL012]
- International Cooperation Project of Qinghai Province [2018-HZ-806, 2017-HZ-806]
- Qinghai Key Laboratory of Tibetan Medicine Research [2017-ZJ-Y11]
- National Natural Science Foundation of China [21302109, 21302110]
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A convenient visible-light-induced method for the synthesis of thiocarbamates from isocyanides, thiols, and water has been developed under mild reaction conditions. The present protocol offers a cost-effective and operationally straightforward approach to the various thiocarbamates in moderate to good yields by simple use of cheap Rose Bengal as the photocatalyst and water as the reaction reagent as well as an environmentally benign cosolvent.
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