4.8 Article

Rh(III)-Catalyzed C-C Coupling of Diverse Arenes and 4-Acyl-1-sulfonyltriazoles via C-H Activation

Journal

ORGANIC LETTERS
Volume 20, Issue 16, Pages 4946-4949

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b02078

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Funding

  1. Dalian Institute of Chemical Physics (CAS)
  2. NSFC [21525208, 42472186]

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4-Acyl-1-sulfonyltriazoles act as versatile carbene reagents in Cp*Rh(III)-catalyzed ortho-selective coupling with arenes via C-H activation. The coupling led to olefination with possible cyclization, depending on the nature of the arene.

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