Journal
ORGANIC LETTERS
Volume 20, Issue 15, Pages 4554-4557Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b01849
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Funding
- National Natural Science Foundation [21772066, 21572229]
- Fundamental Research Funds for the Central Universities
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An asymmetric oxidative C-N bond-forming reaction is developed using a chiral diiodospirobiindane derivative as the catalyst and mCPBA as a terminal oxidant. The protocol is based on an asymmetric desymmetrization strategy and affords lactams or spirolactams according to the different substituents on the substrates. The products are obtained in good yields and moderate to high enantioselectivities.
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