Journal
ORGANIC LETTERS
Volume 20, Issue 17, Pages 5126-5129Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b01995
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Funding
- National Nature Science Foundation of China [21101085]
- Program for Liaoning Innovative Talents in University [LR2017021]
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Rhodium(III)-catalyzed remote meta-selective C-H alkenylation of phenol derivatives has been developed using a traceless organosilicon template as the directing group. This transformation proceeds smoothly with good yields and high meta-selectivities toward a series of phenol and alkene substrates. In addition, this protocol provides an effective strategy for late-stage transformations of various meta-alkenylated aromatic compounds.
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