Journal
ORGANIC LETTERS
Volume 20, Issue 15, Pages 4531-4535Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b01833
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Funding
- National Science Foundation of China [21332003, 21772043]
- Program for Guangdong Introducing Innovative and Entrepreneurial Teams [2016ZT06Y337]
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An asymmetric strategy for the construction of chiral sulfur-containing spirooxindole-fused heterocycles was achieved via a rhodium(II)/chiral phosphoric acid-cocatalyzed reaction between 2-mercaptophenyl ketones and 3-diazooxindoles. With this method, a series of spirooxindole-thiaindan derivatives bearing two contiguous quaternary carbon stereogenic centers were obtained in high yields with high diastereoselectivities and high-to-excellent enantioselectivities.
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