4.8 Article

Synthesis of o-Arylenediamines through Elemental Sulfur-Promoted Aerobic Dehydrogenative Aromatization of Cyclohexanones with Arylamines

Journal

ORGANIC LETTERS
Volume 20, Issue 17, Pages 5470-5473

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b02387

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Funding

  1. National Natural Science Foundation of China [21572194, 21602187]
  2. Collaborative Innovation Center of New Chemical Technologies for Environmental Benignity and Efficient Resource Utilization
  3. Scientific Research Fund of Hunan Provincial Education Department [16B251]

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Herein, the first elemental sulfur-promoted aerobic dehydrogenative aromatization of cyclohexanones is described that provides novel access to synthetically useful o-arylenediamines. This protocol complements previous palladium- and iodine-catalyzed diarylamine formation from cyclohexanones and anilines.

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