Journal
ORGANIC LETTERS
Volume 20, Issue 18, Pages 5826-5830Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b02520
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Funding
- JSPS KAKENHI [16K05769, 18H04245]
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A synthetic route to chiral selenazolines from readily available N-acyloxazolidinones via a selenative rearrangement of a chiral cyclic skeleton is reported. The reaction proceeds in the presence of elemental selenium, a hydrochlorosilane, and an amine. Although the stability of the obtained selenazoline products is relatively low, a wide range of selenazolines was successfully prepared.
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