Journal
ORGANIC LETTERS
Volume 16, Issue 4, Pages 1240-1243Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol500374e
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- ICSN
- CNRS
- Labex Charmmmat
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A photoredox-catalzyed trifluoromethylation of enecarbamates process is reported. This pathway uses Togni's reagent as the CF3 source and follows a radical/cationic pathway. Under the optimized conditions using [Ru(bpy)(3)(PF6)(2)] as the photocatalyst, a wide range of substituted enecarbamates can readily be difunctionalized by means of various O, N, and C nudeophiles.
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