Journal
ORGANIC LETTERS
Volume 16, Issue 19, Pages 5228-5231Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol502693r
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Funding
- Thomas F. & Kate Miller Jeffress Memorial Trust [J-808]
- NSFC [21372159]
- University Paris Diderot
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A palladium-catalyzed asymmetric decarboxylative allylic alkylation of allyl 2,2-diphenylglycinate imines using (S,S)-f-binaphane as a chiral supporting ligand has been developed. This transformation allows for decarboxylative generation and enantioselective allylation of nonenolate a-imino (2-azaallyl anions) to afford alpha-aryl homoallylic imines.
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