Journal
ORGANIC LETTERS
Volume 16, Issue 3, Pages 664-667Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol4032649
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Funding
- NSFC [21322206, 21132005]
- SSTC [13JC1402200]
- Program for Changjiang Scholars and Innovative Research Team in University
- Texas State University-San Marcos
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Two unexpected chiral organometallic triangles rather than squares from newly designed 90 degrees chiral di-Pt(II) acceptors were obtained through coordination-driven self-assembly. Their structures were well characterized by multinuclear NMR (H-1 and P-31) and variable-temperature NMR experiments, ESI-TOF-MS, and elemental analysis. The PM6 semiempirical molecular simulation was employed for the interpretation of the formation and stability of such chiral triangles.
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