Journal
ORGANIC LETTERS
Volume 16, Issue 5, Pages 1394-1397Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol500157b
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Funding
- NSFC [91213303, 21102141, 21272107, 21202072]
- National S&T Major Project of China
- Fundamental Research Funds for the Central Universities [860976, 861188]
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The first example of a highly enantioselective vinylogous Michael-type reaction of beta,beta-disubstituted nitroalkenes is disclosed. A series of biologically important chiral oxindoles, featuring a trifluoromethylated all-carbon quaternary chiral center, were obtained in good yields with excellent enantioselectivities (up to >99% ee).
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