Journal
ORGANIC LETTERS
Volume 16, Issue 15, Pages 4056-4058Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol5018849
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Funding
- National Natural Science Foundation of China [21302236]
- Fundamental Research Funds for the Central Universities [CDJRC11220001, CQDXWL-2013-023]
- Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education Ministry [[2013]693]
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A three-component reaction of triethoxysilanes, sulfur dioxide, and hydrazines catalyzed by copper(II) acetate is reported, leading to N-aminosulfonamides in good yields. Not only triethoxy(aryl)silanes but also triethoxy(alkyl)silanes are compatible during the process of insertion of sulfur dioxide. Additionally, diethoxydiarylsilanes are suitable under the conditions as well.
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