4.8 Article

Asymmetric Synthesis of Planar Chiral Ferrocenes by Enantioselective Intramolecular C-H Arylation of N-(2-Haloaryl)ferrocenecarboxamides

Journal

ORGANIC LETTERS
Volume 16, Issue 20, Pages 5336-5338

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol502520b

Keywords

-

Funding

  1. National Natural Science Foundation of China [21202095]
  2. Program for Science & Technology Innovation Talents in Universities of Henan Province [14HASTIT016]

Ask authors/readers for more resources

The palladium-catalyzed intramolecular C-H arylation reaction of N-(2-bromoaryl)ferrocenecarboxamides furnishes planar chiral ferrocene derivatives. TADDOL-derived phosphoramide ligands induce enantioselectivities ranging from 91:9 to 98:2 er.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.8
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

No Data Available
No Data Available