Journal
ORGANIC LETTERS
Volume 17, Issue 1, Pages 162-165Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol5033859
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Funding
- National Science Foundation [CHE-1111316, CHE-1401700]
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TiO2-supported nanosize gold particles catalyze the hydration of alkynes using morpholine as a basic cocatalyst. Unlike most homogeneous cationic gold catalysts, the TiO2-Au/morpholine system is weakly basic and is compatible with acid-sensitive functional groups (e.g., silyl ethers, ketals) or with a strongly coordinating group such as pyridine. Whats more, this gold catalyst can be recycled by simple filtration and works well in flow reactors.
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